You're not tying into the alternator, per se, you are tying into your staring battery. The alternator charges this battery via a smaller gage wire, as the amount of current flowing between alternator and battery is small relative to what flows between the battery and other things such as the starter.
Really, this is pretty simple. There are dozens of images here and many have already put a fair amount of effort into the answers and probably aren't going to repeat that effort every time someone asks, so do some searches and surf and maybe pick some other things up on the way.
Don't spend too much on your isolator. Even though a bunch of unnecessary voodoo high end options exist, their benefit is near zero. The Mercedes isolator found in vehicles with the aux battery option can be found in the aftermarket equivalent for about $20.
Basically, as posted above, you are hooking into your staring battery, the positive post, with an isolator and ~250 amp fuse in between. Mercedes uses 2 gage wire for this.
You have 3 posts under the driver's seat with full time power, and switched power. Do some homework on these terminals. They are meant for all accessories to be wired into. Run your isolator off one of these 3 posts.
Good luck,